Holders Liverpool crashed out of the Champions League after being taken to extra-time at Anfield.
Jurgen Klopp’s men lost 3-2 to Atletico Madrid in the second leg of their last-16 match.
Llorente scored a double and Alvaro Morata struck the decisive goal in the 120th minute to give the Spanish side a 4-2 aggregate victory.
Elsewhere, Paris Saint-Germain progressed to the quarter-finals with a 3-2 aggregate win over Borussia Dortmund.
Trailing 2-1 from the first leg in Dortmund, the Ligue 1 champions levelled the tie when Neymar netted just before the half-hour mark and Juan Bernat gave them the lead in first-half stoppage time.
Raphinha, Fermin score as Barcelona beat Athletic in home opener
Chelsea and Fulham reach League Cup third round as Welbeck scores on debut
PSG to meet Barca, Man City as Champions League draw throws up marquee ties
Abbas gives Pakistan slight edge as England battle back at Lord's
UEFA suspends FIFA boycott threat but steps up pressure on world body
